The influence of brewing method on bioactive compounds residues in spent coffee grounds of different roasting degree and geographical origin

The content of bioactive compounds in spent coffee grounds (SGC) was studied. SGC were obtained from Coffea arabica beans of different roasting degrees (light and dark) and different geographical origins (Nicaragua, Columbia and Mexico) processed using four brewing methods (mocha, filtered, drip and infusion). The highest caffeine and chlorogenic acid contents were determined in filtered spent coffee extracts. All extracts of light roasted spent coffee grounds showed lower browning index levels in comparison to that from dark roasted spent coffee grounds. Generally, the highest content of total polyphenolic compounds and highest antioxidant capacity were determined in extracts prepared in drip. In conclusion, the results obtained in this study indicate that the spent coffee grounds produced of domestic levels, especially those obtained from filter coffeemaker, could be considered as a good source of natural antioxidants.     

基于改进LFM算法的主动解列断面搜索方法

针对传统解列断面算法复杂度高的问题,提出一种基于改进LFM算法的解列断面搜索方式。首先,基于节点间电气联系和能量转移分布熵完成电网加权复杂网络建模;其次,基于主动解列断面约束条件,对LFM算法做适应性改良;最后,通过改进LFM算法得到解列断面,并在IEEE39节点系统中验证了算法有效性。仿真结果表明,改进LFM算法可充分考虑传统解列断面的约束条件,在算法具有较低复杂度的同时对系统运行状态更强的适应性。     

Corrosion of Li-ion battery cathode materials on mullite insulation materials during calcination

A specially designed experimental device was used in laboratory to investigate the corrosion of mullite during the calcination of Li(Ni_xCo_yMn_z)O₂ (LNCM) materials. The anti-corrosion tests were carried out at 1000, 1100, 1200 and 1300 °C, and characterized with X-ray diffraction and scanning electron microscopy. The influence of temperature on the interactions between mullite insulation materials and LNCM materials was determined. In addition, the high-temperature creep properties of the mullite insulation materials before and after corrosion were tested. The laboratory scale tests, thermodynamic and kinetic calculations allowed a more comprehensive understanding of the evolution of the mullite insulation materials during serving for the roasting process of LNCM materials. Through this research, it is suggested that the upgrading of the kiln lining in the lithium battery industry should select materials with excellent resistance to alkali corrosion, especially excellent resistance to Li⁺ corrosion.     

High-entropy ferroelastic rare-earth tantalite ceramic: (Y0.2Ce0.2Sm0.2Gd0.2Dy0.2)TaO4

In this study, high-entropy rare-earth tantalate ceramics (Y_0.2Ce_0.2Sm_0.2Gd_0.2Dy_0.2)TaO₄ ((5RE_0.2)TaO₄) have been successfully fabricated. The possibility of formation of (5RE_0.2)TaO₄ was verified via first-principles calculations. In addition, the phase structure, ferroelastic toughening mechanism, thermophysical, and mechanical properties were systematically investigated. The (5RE_0.2)TaO₄ ceramics have lower phonon thermal conductivity (1.2–2.6 W·m^–1·K^–1) in the entire temperature range than that of RETaO₄ and YSZ. (5RE_0.2)TaO₄ has a higher fracture toughness and lower brittleness index than YSZ. The thermal expansion coefficients of (5RE_0.2)TaO₄ are as high as 10.3 × 10^-6 K^–1 at 1200°C and Young's modulus is 66–189 GPa, and thus, (5RE_0.2)TaO₄ possesses great potential for application in thermal barrier coatings (TBCs).     

Chemical Bonding by the Chemical Orthogonal Space of Reactivity

The fashionable Parr–Pearson (PP) atoms-in-molecule/bonding (AIM/AIB) approach for determining the exchanged charge necessary for acquiring an equalized electronegativity within a chemical bond is refined and generalized here by introducing the concepts of chemical power within the chemical orthogonal space (COS) in terms of electronegativity and chemical hardness. Electronegativity and chemical hardness are conceptually orthogonal, since there are opposite tendencies in bonding, i.e., reactivity vs. stability or the HOMO-LUMO middy level vs. the HOMO-LUMO interval (gap). Thus, atoms-in-molecule/bond electronegativity and chemical hardness are provided for in orthogonal space (COS), along with a generalized analytical expression of the exchanged electrons in bonding. Moreover, the present formalism surpasses the earlier Parr–Pearson limitation to the context of hetero-bonding molecules so as to also include the important case of covalent homo-bonding. The connections of the present COS analysis with PP formalism is analytically revealed, while a numerical illustration regarding the patterning and fragmentation of chemical benchmarking bondings is also presented and fundamental open questions are critically discussed.     

Characterization of Bi2O3 thin films for doping photoluminescent Er3+ ions

Undoped and Er³⁺-doped Bi₂O₃ thin films were sputter-deposited on Si(100) substrates. Sufficiently oxidized Bi₂O₃ films with refractive indices between 2.17?2.23 were obtained at a wavelength of 633 nm; these values are comparable to those of bulk Bi₂O₃ crystals. While the film composition was stable for deposition temperatures between room temperature (RT) and 450 °C, the refractive index steeply decreased above 450 °C and reached 1.4 at 600 °C. The lowering of the optical transmittance spectra indicated aggregation of metallic Bi and darkening of the film. All films exhibited X-ray diffraction patterns of α-Bi₂O₃. The direct and indirect bandgap energies derived from the Tauc plots were 3.4–3.7 eV and 1.9–2.5 eV, respectively, depending on the O₂ flow rate and deposition temperature. Upon excitation of Er³⁺-doped Bi₂O₃ films at 532 nm, Er³⁺ emissions peaking at 1537 and 1541 nm appeared, and the photoluminescence spectra included fine structures reflecting crystal-field splitting. Resonant excitation of Er³⁺ 4f levels and indirect excitation via the defect levels of Bi₂O₃ followed by energy transfer to Er³⁺ contributed to the emission. The films deposited at RT with Er concentrations of 2 at.% had the emission intensity of Er³⁺, but concentration quenching strongly suppressed the Er³⁺ emission because the doped Er³⁺ ions stayed inside the Bi₂O₃ crystals. At deposition temperatures above 400 °C, the concentration quenching was mitigated possibly because out-diffusion of Er³⁺ ions reduced the effective number of Er³⁺ ions in the Bi₂O₃ crystalline domains.     

Rubber's dissipated energy quantification used in vibratory insulation and protection systems

In vibratory protection and insulation systems, the major problem consist to choose suitable passive elements (spring, damper, others), which are inserted between the resonator and the exciter which have the role of preventing or reducing the transmission of dynamic forces. This work consists of characterizing a synthetic rubber (SR) sample of hollow circular shape (design requirement) by determining the coefficient of energy dissipation at an average ambient temperature of 20°C with a humidity of 25%. The mechanical load and discharge tests make it possible to draw hysteresis curves through which the dissipation coefficient will be determined, the load values is between 500 and 1000 N, with 30, 60, and 90 mm/min loading speeds and a number of cycles 2, 3, and 5, these values have been chosen so as not to cause the effect of cyclic hardening and softening and also to take into consideration, that the vibration limits movement at 3 cycles, which makes this test different from other tests such as fatigue. The processing of different curves, allows to determine energy dissipation coefficient of rubber specimen and also to examine its variation as a function of load, loading speed, and number of cycles; it is possible to determine other characteristics from this coefficient, such as, damping ratio, dynamic amplification factor, and so on, necessary to study efficiency of protection systems, design, and manufacture, based on the curve of transmissibility of dynamic forces to evaluate performance rubber conditions use.     

灾害孤岛潜势风险分群与降雨警戒值探讨

台湾本身地貌特性以及近年来强降雨事件发生频繁,促使山区地带发生复合式灾害,如崩塌、泥石流与山洪等,因此灾害孤岛效应有必要仿效泥石流以及洪水灾害,制定出参考警戒值以及警戒线,将有助于防灾决策、救难资源投入以及灾害风险判释。本文针对台湾发生过灾害孤岛效应的114个村进行分析,且着重于首次发生灾害的台风降雨事件。首先通过群集分析并依照各样本的6个灾因指标进行分类,群集结果显示可分为8个群,并再以象限分布描述各群的潜势相对风险。采用2004—2015年台风降雨事件的观测雨量数据,并利用距离反比权重法,得出各村的累积降雨量(R)与最大时雨量(I)。整合各群集样本雨量数据后,使用台湾水土保持局使用的RTI模式概念,计算出各群集之RTImin、RTI30、RTI50和RTI70,以绘制低风险区(0～30%)、中风险区(30～70%)和高风险区(70%～100%),其中着重探讨灾害孤岛事件的下限值RTImin,以便可得知最易发生灾害的群集。结果显示,各群的潜势风险反映RTImin的效果良好,如潜势风险越高则其RTImin值越低,即雨量驱动灾害发生的条件较低。群集中,第1与2群为低风险群、第3、5与6群为中风险群、第4、7与8群为高风险群,仅第5群无法透过RTImin验证潜势风险关系,故本文挑选的6项灾因指标,为辨别灾害孤岛效应潜势等级的重要因子。     

蜂窝梁的稳定性能研究进展

对蜂窝梁破坏模式的研究表明，失稳是其结构性能失效的重要破坏模式。为此，在回顾蜂窝梁结构特性研究的基础上，总结归纳了蜂窝梁失稳的3种主要模式：整体弯扭失稳、梁墩屈曲、畸变屈曲。结合国内外近30多年来对蜂窝梁稳定性的试验研究成果，对影响蜂窝梁稳定性的主要因素进行分析。采用蒙特卡洛法得到纯弯简支蜂窝梁弯扭失稳临界荷载的概率分布和影响因子的敏感度。将部分具有代表性的试验成果与欧洲规范EN 1993-1-1计算结果进行对比，根据中国规范GB 50068—2001《建筑结构可靠度设计统一标准》提供的抗力分项系数，计算了不同荷载组合下蜂窝梁整体弯扭失稳临界荷载的可靠度指标，为国内规范的制订提供依据。最后，总结了当前蜂窝梁稳定性研究中存在的不足，指明了进一步研究的方向。     

Elliptical distribution-based weight-determining method for ordered weighted averaging operators

The ordered weighted averaging (OWA) operators play a crucial role in aggregating multiple criteria evaluations into an overall assessment supporting the decision makers’ choice. One key point steps is to determine the associated weights. In this paper, we first briefly review some main methods for determining the weights by using distribution functions. Then we propose a new approach for determining OWA weights by using the regular increasing monotone quantifier. Motivated by the idea of normal distribution-based method to determine the OWA weights, we develop a method based on elliptical distributions for determining the OWA weights, and some of its desirable properties have been investigated.